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  Palladium(III)-catalyzed fluorination of arylboronic acid derivatives

Mazzotti, A. R., Campbell, M. G., Tang, P., Murphy, J. M., & Ritter, T. (2013). Palladium(III)-catalyzed fluorination of arylboronic acid derivatives. Journal of the American Chemical Society, 135(38), 14012-14015. doi: 10.1021/ja405919z.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-002C-3BF9-C Version Permalink: https://hdl.handle.net/11858/00-001M-0000-002C-3BFA-A
Genre: Journal Article

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 Creators:
Mazzotti, Anthony R.1, Author
Campbell, Michael G.1, Author
Tang, Pingping1, Author
Murphy, Jennifer M.1, Author
Ritter, Tobias1, Author           
Affiliations:
1Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford St., Cambridge, MA 02138 (USA), ou_persistent22              

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Free keywords: COPPER-MEDIATED FLUORINATION; C-H FLUORINATION; REDUCTIVE ELIMINATION; ARYL FLUORIDES; BOND FORMATION; ELECTROPHILIC FLUORINATION; PD(III) COMPLEXES; PALLADIUM; DEOXYFLUORINATION; CONVERSION
 Abstract: A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is presented. The reaction is operationally simple and amenable to multigram-scale synthesis. Evaluation of the reaction mechanism suggests a single-electron-transfer pathway, involving a Pd(III) intermediate that has been isolated and characterized.

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Language(s): eng - English
 Dates: 2013-06-122013-09-162013-09-25
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/ja405919z
ISSN: 0002-7863
 Degree: -

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Title: Journal of the American Chemical Society
  Other : J. Am. Chem. Soc.
  Abbreviation : JACS
Source Genre: Journal
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Affiliations:
Publ. Info: Washington, DC : American Chemical Society
Pages: 4 Volume / Issue: 135 (38) Sequence Number: - Start / End Page: 14012 - 14015 Identifier: ISSN: 0002-7863
CoNE: https://pure.mpg.de/cone/journals/resource/954925376870