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  The electrochemical reduction of a cadmium cryptate on a mercury electrode in acetonitrile.

Stroka, J., Cox, B. G., & Schneider, H. (1989). The electrochemical reduction of a cadmium cryptate on a mercury electrode in acetonitrile. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 266(2), 337-348. doi:10.1016/0022-0728(89)85079-X.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-3E40-3 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-3E43-E
Genre: Journal Article

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2382631.pdf (Publisher version), 749KB
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Stroka, J.1, Author              
Cox, B. G., Author
Schneider, H.1, Author              
Affiliations:
1Research Group Electrochemistry and Reaction Kinetics in Solution, MPI for biophysical chemistry, Max Planck Society, ou_578550              

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 Abstract: The reduction of the Cd(2,2,2)2+ complex has been studied in acetonitrile using polarography, chronocoulometry, and cyclic voltammetry. The corresponding kinetic parameters have been calculated and are compared with those obtained for the solvated cadmium cation in the same solvent. The study of the electrochemical reduction mechanism showed that the final stable products are the free ligand (2,2,2) and cadmium-amalgam. The stability constant of the cadmium cryptate in acetonitrile has been estimated as log Ks = 17.3 from the electrochemical measurements.

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Language(s): eng - English
 Dates: 1989-07-25
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1016/0022-0728(89)85079-X
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Title: Journal of Electroanalytical Chemistry and Interfacial Electrochemistry
Source Genre: Journal
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Pages: - Volume / Issue: 266 (2) Sequence Number: - Start / End Page: 337 - 348 Identifier: -