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  (H3O)3Sb2Br9: the first member of the M3E2X9 structure family with oxonium cations

Chang, J.-H., Doert, T., & Ruck, M. (2016). (H3O)3Sb2Br9: the first member of the M3E2X9 structure family with oxonium cations. Acta Crystallographica, Section C: Crystal Structure Communications, 72, 966-970. doi:10.1107/S2053229616017198.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-3EBB-F Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-BD15-5
Genre: Journal Article

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 Creators:
Chang, Jen-Hui1, Author
Doert, Thomas1, Author
Ruck, Michael2, Author              
Affiliations:
1External Organizations, ou_persistent22              
2Michael Ruck, Max Planck Fellow, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863444              

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 Abstract: (H3O)(3)Sb2Br9 [trihydroxonium enneabromidodiantimonate(III)] is the first representative of the M3E2X9 family (M = cation, E = Sb and Bi, and X = Br and I) with oxonium cations. The metastable compound was obtained in trace amounts from a solution of CsBr and SbBr3 in concentrated aqueous HBr. Single crystals were isolated from the mother liquor and investigated by single-crystal X-ray diffraction at 100 K. (H3O)(3)Sb2Br9 crystallizes with the Tl3Bi2I9 structure type, which is a distorted defect variant of cubic perovskite. The crystal structure comprises characteristic infinity(2)[SbBr3Br3/2] double layers of corner-sharing SbBr6 octahedra with a [001] stacking direction. Due to the small size of the H3O+ cation and O-H center dot center dot center dot Br hydrogen bonding, the octahedra are tilted.

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Language(s): eng - English
 Dates: 2016-10-262016-10-26
 Publication Status: Published in print
 Pages: -
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 Table of Contents: -
 Rev. Method: -
 Identifiers: ISI: 000390259200007
DOI: 10.1107/S2053229616017198
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Title: Acta Crystallographica, Section C: Crystal Structure Communications
  Other : Acta Crystallogr., Sect. C: Cryst. Struct. Commun.
Source Genre: Journal
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Publ. Info: Copenhagen, Denmark : Published for International Union of Crystallography by Munksgaard
Pages: - Volume / Issue: 72 Sequence Number: - Start / End Page: 966 - 970 Identifier: ISSN: 0108-2701
CoNE: https://pure.mpg.de/cone/journals/resource/110987085479123