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  (H3O)3Sb2Br9: the first member of the M3E2X9 structure family with oxonium cations

Chang, J.-H., Doert, T., & Ruck, M. (2016). (H3O)3Sb2Br9: the first member of the M3E2X9 structure family with oxonium cations. Acta Crystallographica, Section C: Crystal Structure Communications, 72, 966-970. doi:10.1107/S2053229616017198.

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Datensatz-Permalink: https://hdl.handle.net/11858/00-001M-0000-002C-3EBB-F Versions-Permalink: https://hdl.handle.net/11858/00-001M-0000-002C-3F9C-D
Genre: Zeitschriftenartikel

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 Urheber:
Chang, Jen-Hui1, Autor
Doert, Thomas1, Autor
Ruck, Michael2, Autor           
Affiliations:
1External Organizations, ou_persistent22              
2Michael Ruck, Max Planck Fellow, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863444              

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 Zusammenfassung: (H3O)(3)Sb2Br9 [trihydroxonium enneabromidodiantimonate(III)] is the first representative of the M3E2X9 family (M = cation, E = Sb and Bi, and X = Br and I) with oxonium cations. The metastable compound was obtained in trace amounts from a solution of CsBr and SbBr3 in concentrated aqueous HBr. Single crystals were isolated from the mother liquor and investigated by single-crystal X-ray diffraction at 100 K. (H3O)(3)Sb2Br9 crystallizes with the Tl3Bi2I9 structure type, which is a distorted defect variant of cubic perovskite. The crystal structure comprises characteristic infinity(2)[SbBr3Br3/2] double layers of corner-sharing SbBr6 octahedra with a [001] stacking direction. Due to the small size of the H3O+ cation and O-H center dot center dot center dot Br hydrogen bonding, the octahedra are tilted.

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Sprache(n): eng - English
 Datum: 2016-10-262016-10-26
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: -
 Identifikatoren: ISI: 000390259200007
DOI: 10.1107/S2053229616017198
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Titel: Acta Crystallographica, Section C: Crystal Structure Communications
  Andere : Acta Crystallogr., Sect. C: Cryst. Struct. Commun.
Genre der Quelle: Zeitschrift
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: Copenhagen, Denmark : Published for International Union of Crystallography by Munksgaard
Seiten: - Band / Heft: 72 Artikelnummer: - Start- / Endseite: 966 - 970 Identifikator: ISSN: 0108-2701
CoNE: https://pure.mpg.de/cone/journals/resource/110987085479123