English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Lignin-based polymeric surfactants for emulsion polymerization

Schmidt, B. V. K. J., Molinari, V., Esposito, D., Tauer, K., & Antonietti, M. (2017). Lignin-based polymeric surfactants for emulsion polymerization. Polymer, 112, 418-426. doi:10.1016/j.polymer.2017.02.036.

Item is

Basic

show hide
Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-6254-B Version Permalink: http://hdl.handle.net/21.11116/0000-0005-DD21-D
Genre: Journal Article

Files

show Files
hide Files
:
2395137.pdf (Publisher version), 3MB
 
File Permalink:
-
Name:
2395137.pdf
Description:
-
Visibility:
Restricted (Max Planck Institute of Colloids and Interfaces, MTKG; )
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-
:
Manuskript.pdf (Any fulltext), 2MB
 
File Permalink:
-
Name:
Manuskript.pdf
Description:
-
Visibility:
Restricted (Max Planck Institute of Colloids and Interfaces, MTKG; )
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show

Creators

show
hide
 Creators:
Schmidt, Bernhard V. K. J.1, Author              
Molinari, Valerio2, Author              
Esposito, Davide2, Author              
Tauer, Klaus3, Author              
Antonietti, Markus4, Author              
Affiliations:
1Bernhard Schmidt, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_2149676              
2Davide Esposito, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863315              
3Klaus Tauer, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863320              
4Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863321              

Content

show
hide
Free keywords: -
 Abstract: A non-ionic surfactant system is synthesized by standard grafting of poly (ethylene oxide) from renewable lignin fragments and used for the emulsion polymerization of styrene. The lignin precursors is formed by hydrogenolysis and utilized as initiator for the oxyanionic polymerization of ethylene oxide leading to amphiphilic polymers, very similar to standard nonionic surfactant synthesis. Subsequently, the formed amphiphilic polymers are employed as stabilizers in the heterophase polymerization of styrene with various initiators. Poly (styrene) latexes with solids contents of up to 21% depending on stabilizer concentration have been obtained. Stabilizer efficiencies and performances were nicely comparable with those of nonylphenol-based, non-ionic industrial performance surfactants.

Details

show
hide
Language(s):
 Dates: 2017-02-102017-03-10
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: DOI: 10.1016/j.polymer.2017.02.036
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Polymer
  Other : Polymer
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Guildford, England : Elsevier
Pages: - Volume / Issue: 112 Sequence Number: - Start / End Page: 418 - 426 Identifier: ISSN: 0032-3861