English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  The Triply Deprotonated Acetonitrile Anion CCN3− Stabilized in a Solid

Jach, F., Brückner, S. I., Ovchinnikov, A., Isaeva, A., Bobnar, M., Groh, M. F., et al. (2017). The Triply Deprotonated Acetonitrile Anion CCN3− Stabilized in a Solid. Angewandte Chemie International Edition in English, 56, 2919-2922. doi:10.1002/anie.201611177.

Item is

Basic

show hide
Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-60BC-2 Version Permalink: http://hdl.handle.net/21.11116/0000-0000-FCF6-F
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Jach, Franziska1, Author              
Brückner, Stephan Ingmar2, Author
Ovchinnikov, Alexander1, Author              
Isaeva, Anna2, Author
Bobnar, Matej1, Author              
Groh, Matthias Friedrich2, Author
Brunner, Eike2, Author
Höhn, Peter3, Author              
Ruck, Michael4, Author              
Affiliations:
1Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
2External Organizations, ou_persistent22              
3Peter Höhn, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863419              
4Michael Ruck, Max Planck Fellow, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863444              

Content

show
hide
Free keywords: acetonitriletriide, nitridometalates, NMR spectroscopy, solid-state synthesis, structure elucidation
 Abstract: The unprecedented, fully deprotonated form of acetonitrile, the acetonitriletriide anion CCN3−, is experimentally realized for the first time in the stabilizing bulk host framework of the Ba5[TaN4][C2N] nitridometalate via a one-pot synthesis from the elements under moderate conditions (920 K). The molecular structure of this long-sought acetonitrile derivative is confirmed by X-ray diffraction, as well as NMR, IR, and Raman spectroscopy. The anion is isoelectronic to the CO2 molecule, and, in contrast to acetonitrile (H3C−C≡N), the electron pairs are shifted towards two double bonds, that is, [C=C=N]3−.

Details

show
hide
Language(s): eng - English
 Dates: 2017-02-032017-02-03
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: DOI: 10.1002/anie.201611177
BibTex Citekey: ANIE:ANIE201611177
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Angewandte Chemie International Edition in English
  Other : Angewandte Chemie, International Edition in English
  Other : Angew. Chem., Int. Ed. Engl.
  Other : Angew. Chem. Int. Ed. Engl.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 56 Sequence Number: - Start / End Page: 2919 - 2922 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833