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  The Triply Deprotonated Acetonitrile Anion CCN3− Stabilized in a Solid

Jach, F., Brückner, S. I., Ovchinnikov, A., Isaeva, A., Bobnar, M., Groh, M. F., et al. (2017). The Triply Deprotonated Acetonitrile Anion CCN3− Stabilized in a Solid. Angewandte Chemie, 129, 2965-2968. doi:10.1002/ange.201611177.

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 Creators:
Jach, Franziska1, Author           
Brückner, Stephan Ingmar2, Author
Ovchinnikov, Alexander1, Author           
Isaeva, Anna2, Author
Bobnar, Matej1, Author           
Groh, Matthias Friedrich2, Author
Brunner, Eike2, Author
Höhn, Peter3, Author           
Ruck, Michael4, Author           
Affiliations:
1Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
2External Organizations, ou_persistent22              
3Peter Höhn, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863419              
4Michael Ruck, Max Planck Fellow, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863444              

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Free keywords: Acetonitriltriid, Festkörpersynthesen, Nitridometallate, NMR-Spektroskopie, Strukturaufklärung
 Abstract: The unprecedented, fully deprotonated form of acetonitrile, the acetonitriletriide anion CCN3−, is experimentally realized for the first time in the stabilizing bulk host framework of the Ba5[TaN4][C2N] nitridometalate via a one-pot synthesis from the elements under moderate conditions (920 K). The molecular structure of this long-sought acetonitrile derivative is confirmed by X-ray diffraction, as well as NMR, IR, and Raman spectroscopy. The anion is isoelectronic to the CO2 molecule, and, in contrast to acetonitrile (H3C−C≡N), the electron pairs are shifted towards two double bonds, that is, [C=C=N]3−.

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Language(s): eng - English
 Dates: 2017-02-032017-02-03
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1002/ange.201611177
BibTex Citekey: ANGE:ANGE201611177
 Degree: -

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Title: Angewandte Chemie
  Abbreviation : Angew. Chem.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 129 Sequence Number: - Start / End Page: 2965 - 2968 Identifier: ISSN: 0044-8249
CoNE: https://pure.mpg.de/cone/journals/resource/954926979058_1