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  Identification of absolute geometries of cis and trans molecular isomers by Coulomb explosion imaging.

Ablikim, U., Bomme, C., Xiong, H., Savelyev, E., Obaid, R., Kaderiya, B., et al. (2016). Identification of absolute geometries of cis and trans molecular isomers by Coulomb explosion imaging. Scientific Reports, 6: 38202. doi:10.1038/srep38202.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-60D0-1 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-60D3-C
Genre: Journal Article

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 Creators:
Ablikim, U., Author
Bomme, C., Author
Xiong, H., Author
Savelyev, E., Author
Obaid, R., Author
Kaderiya, B., Author
Augustin, S., Author
Schnorr, K., Author
Dumitriu, I., Author
Osipov, T., Author
Bilodeau, R., Author
Kilcoyne, D., Author
Kumarappan, V., Author
Rudenko, A., Author
Berrah, N., Author
Rolles, D.1, Author              
Affiliations:
1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society, ou_578564              

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 Abstract: An experimental route to identify and separate geometric isomers by means of coincident Coulomb explosion imaging is presented, allowing isomer-resolved photoionization studies on isomerically mixed samples. We demonstrate the technique on cis/trans 1,2-dibromoethene (C2H2Br2). The momentum correlation between the bromine ions in a three-body fragmentation process induced by bromine 3d inner-shell photoionization is used to identify the cis and trans structures of the isomers. The experimentally determined momentum correlations and the isomer-resolved fragment-ion kinetic energies are matched closely by a classical Coulomb explosion model.

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Language(s): eng - English
 Dates: 2016-12-02
 Publication Status: Published online
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 Rev. Method: Peer
 Identifiers: DOI: 10.1038/srep38202
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Title: Scientific Reports
Source Genre: Journal
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Pages: 8 Volume / Issue: 6 Sequence Number: 38202 Start / End Page: - Identifier: -