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  Solution behavior of poly(styrene)-block-poly(2-vinylpyridine micelles containing gold nanoparticles

Mössmer, S., Spatz, J. P., Möller, M., Aberle, T., Schmidt, J., & Burchard, W. (2000). Solution behavior of poly(styrene)-block-poly(2-vinylpyridine micelles containing gold nanoparticles. Macromolecules, 33(13), 4791-4798. doi:10.1021/ma992006i.

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Macromol_33_2000_4791.pdf (Any fulltext), 373KB
 
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 Creators:
Mössmer, Stefan, Author
Spatz, Joachim P.1, 2, Author           
Möller, Martin, Author
Aberle, Thomas, Author
Schmidt, Jürgen, Author
Burchard, Walther, Author
Affiliations:
1Cellular Biophysics, Max Planck Institute for Medical Research, Max Planck Society, ou_2364731              
2Biophysical Chemistry, Institute of Physical Chemistry, University of Heidelberg, 69120 Heidelberg, Germany, ou_persistent22              

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 Abstract: Formation and structural transformation of inverse poly(styrene)-block-poly(2-vinylpyridine) micelles whose polyvinylpyridine core was loaded with HAuCl4 or with elementary gold nanoclusters was studied by combined static and dynamic light scattering. A transformation in the morphology from spherical particles (small Rg/Rh ratio) to large anisomeric objects (large Rg/Rh ratio) was observed by decreasing the concentration of the block copolymer below the critical micelle concentration. At this point, the polymer chains are molecularly dispersed and no longer able to prevent uncontrolled growth of the gold nanoclusters.

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Language(s): eng - English
 Dates: 2000-03-011999-11-302000-06-022000
 Publication Status: Issued
 Pages: 8
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 Identifiers: ISI: ISI:000087900800028
ISSN: 0024-9297
DOI: 10.1021/ma992006i
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Title: Macromolecules
Source Genre: Journal
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Publ. Info: Washington, D.C. : American Chemical Society
Pages: - Volume / Issue: 33 (13) Sequence Number: - Start / End Page: 4791 - 4798 Identifier: ISSN: 0024-9297
CoNE: https://pure.mpg.de/cone/journals/resource/954925421108