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  Mass Spectrometric Coverage of Complex Mixtures: Exploring the Carbon Space of Crude Oil

Vetere, A., & Schrader, W. (2017). Mass Spectrometric Coverage of Complex Mixtures: Exploring the Carbon Space of Crude Oil. ChemistrySelect, 2(3), 849-853. doi:10.1002/slct.201601083.

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 Creators:
Vetere, Alessandro1, Author              
Schrader, Wolfgang1, Author              
Affiliations:
1Service Department Schrader (MS), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445629              

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Free keywords: Analytical Chemistry; carbon space; crude oil; High-field FT-Orbitrap; ultra-high resolving mass spectrometry
 Abstract: Mass spectrometry is a powerful tool to investigate complex reactions in complex matrices such as crude oils. However, certain requirements have to be met. Apart from a good instrument sensitivity and mass measurement accuracy, especially a certain minimum mass resolving power of above 500,000 at m/z 1000 needs to be reached to resolve critical peak pairs. If the desired parameters are met, a good coverage of the full compositional space or “carbon space” can be achieved to allow a comprehensive picture of the sample at hand. Here, the performance of a newly introduced High-field Fourier Transform Orbitrap setup with nominal resolving power of 960,000 at m/z 400 is tested against the demands.

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Language(s): eng - English
 Dates: 2017-01-24
 Publication Status: Published online
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/slct.201601083
 Degree: -

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Title: ChemistrySelect
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 2 (3) Sequence Number: - Start / End Page: 849 - 853 Identifier: ISSN: 2365-6549
CoNE: https://pure.mpg.de/cone/journals/resource/2365-6549