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  Plants to polyelectrolytes : theophylline polymers and their microsphere synthesis

Guterman, R., Antonietti, M., & Yuan, J. (2017). Plants to polyelectrolytes: theophylline polymers and their microsphere synthesis. Macromolecular Rapid Communications, 38(8): 1600748. doi:10.1002/marc.201600748.

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 Creators:
Guterman, Ryan1, Author           
Antonietti, Markus2, Author           
Yuan, Jiayin1, Author           
Affiliations:
1Jiayin Yuan, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863318              
2Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863321              

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Free keywords: alkaloid, ionic liquid, polyelectrolyte, poly(ionic liquid), polymer
 Abstract: To extend fossil oil supplies, sustainable feed stocks for the production of useful reagents and polymers should be harnessed. In this regard, chemicals derived from plants are excellent candidates. While the vast majority of plant sources used for polymer science only contain CxHyOz, alkaloids such as caffeine, nicotine, and theophylline possess nitrogen functionality that can provide new functions for bioderived polymers and their synthesis. In this context, the chemistry of theophylline, a natural product found in chocolate and tea, is exploited to create a cationic “poly(theophylline)” in a straightforward fashion for the first time. This work demonstrates how this new polymer can be synthesized and used for the creation of narrowly disperse cationic microspheres.

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 Dates: 2017-02-232017
 Publication Status: Issued
 Pages: -
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 Identifiers: DOI: 10.1002/marc.201600748
arXiv: 1705.04274
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Title: Macromolecular Rapid Communications
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 38 (8) Sequence Number: 1600748 Start / End Page: - Identifier: ISSN: 1022-1336