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  Asymmetric Catalysis of the Carbonyl-Amine Condensation: Kinetic Resolution of Primary Amines.

Das, S., Majumdar, N., De, C. K., Kundu, D. S., Döhring, A., Garczynski, A., et al. (2017). Asymmetric Catalysis of the Carbonyl-Amine Condensation: Kinetic Resolution of Primary Amines. Journal of the American Chemical Society, 139(4), 1357-1359. doi:10.1021/jacs.6b12176.

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Das, Majumdar, De, Kundu, Döhring, Garczynski, List 2017.pdf (Postprint), 527KB
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Das, Majumdar, De, Kundu, Döhring, Garczynski, List 2017.pdf
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 Creators:
Das, Sayantani1, Author           
Majumdar, Nilanjana1, Author           
De, Chandra Kanta1, Author           
Kundu, Dipti Sankar1, Author           
Döhring, Arno1, Author           
Garczynski, Anika1, Author           
List, Benjamin1, Author           
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1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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 Abstract: A Brønsted acid catalyzed kinetic resolution of primary amines is described that is based on the condensation between an amine and a carbonyl compound. 1,3-Diketones react with racemic α-branched amines to furnish the corresponding enantioenriched enaminone and recovered starting material. Good to excellent enantioselectivity was observed with both aromatic and aliphatic primary amines. This process represents the first small-molecule catalyzed kinetic resolution of aliphatic amines.

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Language(s): eng - English
 Dates: 2016-11-252017-01-172017-02-01
 Publication Status: Published in print
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/jacs.6b12176
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Title: Journal of the American Chemical Society
  Other : JACS
  Abbreviation : J. Am. Chem. Soc.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 139 (4) Sequence Number: - Start / End Page: 1357 - 1359 Identifier: ISSN: 0002-7863
CoNE: https://pure.mpg.de/cone/journals/resource/954925376870