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  Hg4O3[ReO4]2, Featuring a 2D Polycationic Framework [Hg4O3]2+ with Tetrahedral Rhenate(VII) Anions Embedded

Prasad, B. E., Nuss, J., Felser, C., & Jansen, M. (2016). Hg4O3[ReO4]2, Featuring a 2D Polycationic Framework [Hg4O3]2+ with Tetrahedral Rhenate(VII) Anions Embedded. Zeitschrift für anorganische und allgemeine Chemie, 642, 1359-1363. doi:10.1002/zaac.201600343.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-AFA9-9 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-BE11-5
Genre: Journal Article

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 Creators:
Prasad, Beluvalli E.1, Author              
Nuss, Juergen2, Author
Felser, Claudia3, Author              
Jansen, Martin1, Author              
Affiliations:
1Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863425              
2External Organizations, ou_persistent22              
3Claudia Felser, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863429              

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 Abstract: New Hg4O3[ReO4](2) was obtained via low temperature synthesis, at 65-70 degrees C. The coarse crystalline, single phase product is pale yellow, starts to decompose at 540 degrees C and sublimes without leaving behind any solid residue at 685 degrees C in an argon atmosphere. Its crystal structure [P2(1)/n (14), a = 7.0104(10), b = 12.5046(18), c = 12.1692(18) angstrom, beta = 91.838(3)degrees, Z = 4] can be rationalized as a stuffed HgRe2 sub lattice, adopting the MgZn2 Laves phase arrangement. The resulting structure after inserting the oxygen atoms consists of heavily corrugated 2D polycationic Hg/O networks stacked along [001] with the tetrahedral oxorhenate(VII) anions accommodated in the folds of individual layers.

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Language(s): eng - English
 Dates: 2016-11-302016-11-30
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: ISI: 000394225800007
DOI: 10.1002/zaac.201600343
 Degree: -

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Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : Journal of Inorganic and General Chemistry
  Other : J. Inorg. Gen Chem.
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
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Publ. Info: Leipzig, Weinheim : Verlag Johann Ambrosius Barth / Wiley-VCH
Pages: - Volume / Issue: 642 Sequence Number: - Start / End Page: 1359 - 1363 Identifier: Other: 1521-3749
ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895