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  Weak Interactions under Pressure: hp-CuBi and Its Analogues

Guo, K., Akselrud, L., Bobnar, M., Burkhardt, U., Schmidt, M., Zhao, J.-T., et al. (2017). Weak Interactions under Pressure: hp-CuBi and Its Analogues. Angewandte Chemie International Edition in English, 56(20), 5620-5624. doi:10.1002/anie.201700712.

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 Creators:
Guo, Kai1, Author           
Akselrud, Lev1, Author           
Bobnar, Matej1, Author           
Burkhardt, Ulrich2, Author           
Schmidt, Marcus3, Author           
Zhao, Jing-Tai4, Author
Schwarz, Ulrich5, Author           
Grin, Yuri6, Author           
Affiliations:
1Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
2Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863422              
3Marcus Schmidt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863415              
4External Organizations, ou_persistent22              
5Ulrich Schwarz, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863423              
6Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863413              

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Free keywords: bismuth, copper, high-pressure high-temperature synthesis, nonpolar compounds, superconductivity
 Abstract: The metastable binary compound hp-CuBi was obtained from the direct chemical reaction between copper and bismuth at a pressure of 5 GPa and a temperature of 720 K. The atomic arrangement comprises slabs of puckered Cu layers sandwiched between Bi planes. The QTAIM charges calculated for compounds of bismuth with transition metals reveal negligible charge transfer for hp-CuBi. Analysis of the chemical bonding with position-space techniques discloses multicenter interactions within the Bi-Cu-Bi slabs and lone-pair interactions of the van der Waals type between these entities. hp-CuBi exhibits metal-type electrical conductivity with superconductivity below Tc=1.3 K.

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Language(s): eng - English
 Dates: 2017-04-202017-04-20
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1002/anie.201700712
 Degree: -

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Title: Angewandte Chemie International Edition in English
  Other : Angewandte Chemie, International Edition in English
  Other : Angew. Chem., Int. Ed. Engl.
  Other : Angew. Chem. Int. Ed. Engl.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 56 (20) Sequence Number: - Start / End Page: 5620 - 5624 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833