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  α-RbO3, a Low Temperature Polymorph of Rubidium Ozonide

Sans, A., Nuss, H., Mohitkar, S., & Jansen, M. (2017). α-RbO3, a Low Temperature Polymorph of Rubidium Ozonide. Zeitschrift für anorganische und allgemeine Chemie, 643(5), 357-359. doi:10.1002/zaac.201600430.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-2221-7 Version Permalink: http://hdl.handle.net/21.11116/0000-0001-01DD-5
Genre: Journal Article

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 Creators:
Sans, Annette1, Author
Nuss, Hanne1, Author
Mohitkar, Shrikant2, Author              
Jansen, Martin2, Author              
Affiliations:
1External Organizations, ou_persistent22              
2Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863425              

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 Abstract: Applying the known procedure for synthesis of alkali metal ozonides, just at a lower temperature, has yielded a new polymorph of rubidium ozonide, -RbO3 [P2(1); a = 436.3(2), b = 595.3(3), c = 548.7(3) pm, = 99.680(7), R = 0.0400, 1184 reflections]. Like previously reported -RbO3, the basic structural arrangement of anions and cations corresponds to the CsCl type of structure, however, the mutual orientation of the ozonide ions is different, in as much as one of the two terminal oxygen atoms is pointing to the adjacent bridging oxygen atom, forming a chain running along the b axis.

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Language(s): eng - English
 Dates: 2017-02-012017-02-01
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: ISI: 000397582300002
DOI: 10.1002/zaac.201600430
 Degree: -

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Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : Journal of Inorganic and General Chemistry
  Other : J. Inorg. Gen Chem.
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
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Publ. Info: Leipzig, Weinheim : Verlag Johann Ambrosius Barth / Wiley-VCH
Pages: - Volume / Issue: 643 (5) Sequence Number: - Start / End Page: 357 - 359 Identifier: Other: 1521-3749
ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895