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  Thermo-analytical Investigations on the Superoxides AO2 (A = K, Rb, Cs), Revealing Facile Access to Sesquioxides A4O6

Merz, P., Schmidt, M., Felser, C., & Jansen, M. (2017). Thermo-analytical Investigations on the Superoxides AO2 (A = K, Rb, Cs), Revealing Facile Access to Sesquioxides A4O6. Zeitschrift für anorganische und allgemeine Chemie, 643(8), 544-547. doi:10.1002/zaac.201700013.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-2A64-6 Version Permalink: http://hdl.handle.net/21.11116/0000-0001-08EB-E
Genre: Journal Article

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 Creators:
Merz, Patrick1, Author              
Schmidt, Marcus2, Author              
Felser, Claudia3, Author              
Jansen, Martin1, Author              
Affiliations:
1Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863425              
2Marcus Schmidt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863415              
3Claudia Felser, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863429              

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Free keywords: Alkali metal oxides; Thermal decomposition; Synthesis of alkali metal sesquioxides; Alkali metals
 Abstract: Rb4O6 and Cs4O6 represent open shell p electron systems, featuring charge, spin, orbital and structural degrees of freedom, which makes them unique candidates for studying the ordering processes related, otherwise exclusively encountered in transition metal based materials. Probing the physical responses has been restrained by the intricacy of synthesizing appropriate amounts of phase pure samples. Tracing the thermal decomposition of respective superoxides has revealed that at least the rubidium and cesium sesquioxides exist in thermodynamic equilibrium, appropriate p-T conditions given. These insights have paved the way to highly efficient and convenient access to Rb4O6 and Cs4O6.

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Language(s): eng - English
 Dates: 2017-03-242017-03-24
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: DOI: 10.1002/zaac.201700013
BibTex Citekey: ZAAC:ZAAC201700013
 Degree: -

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Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : Journal of Inorganic and General Chemistry
  Other : J. Inorg. Gen Chem.
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
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Publ. Info: Leipzig, Weinheim : Verlag Johann Ambrosius Barth / Wiley-VCH
Pages: - Volume / Issue: 643 (8) Sequence Number: - Start / End Page: 544 - 547 Identifier: Other: 1521-3749
ISSN: 0044-2313
CoNE: /journals/resource/954925453895