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  Ultrafast electron diffraction study of single-crystal (EDO-TTF)2SbF6: Counterion effect and dimensionality reduction

Liu, L. C., Jiang, Y., Müller-Werkmeister, H., Lu, C., Moriena, G., Ishikawa, M., et al. (2017). Ultrafast electron diffraction study of single-crystal (EDO-TTF)2SbF6: Counterion effect and dimensionality reduction. Chemical Physics Letters, 683, 160-165. doi:10.1016/j.cplett.2017.05.007.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-49E0-1 Version Permalink: http://hdl.handle.net/21.11116/0000-0001-EAD6-6
Genre: Journal Article

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 Creators:
Liu, Lai Chung1, Author
Jiang, Yifeng1, 2, Author              
Müller-Werkmeister, Henrike1, 2, Author              
Lu, Cheng1, Author
Moriena, Gustavo1, Author
Ishikawa, Manabu3, Author
Nakano, Yoshiaki3, 4, Author
Yamochi, Hideki3, 4, Author
Miller, R. J. Dwayne1, 2, Author              
Affiliations:
1Department of Chemistry, University of Toronto, Canada, 80 St. George St, Toronto M5S 3H6, Canada, ou_persistent22              
2Miller Group, Atomically Resolved Dynamics Department, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society, ou_1938288              
3Research Centre for Low Temperature and Materials Sciences, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan, ou_persistent22              
4Division of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan, ou_persistent22              

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Free keywords: Ultrafast electron diffraction Femtosecond structural dynamics Photoinduced phase transition Singular value decomposition Dimensionality reduction
 Abstract: Ultrafast electron diffraction is a sensitive tool to directly study molecular dynamics in structural detail. Here, we report the influence of counterion size on the photoinduced insulator-to-metal phase transition in two derivatives of the organic salt (EDO-TTF)2XF6. For X = P, three dominant motions are present and the molecules undergo the transition, whereas in the case of X = Sb, only two dominant motions are found and the molecules do not evolve into the metallic state. This reduction in dimensionality is supported by a novel data analysis method involving singular value decomposition of time-resolved electron diffraction data in reciprocal space.

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Language(s): eng - English
 Dates: 2017-05-022017-02-242017-05-042017-09-01
 Publication Status: Published in print
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Identifiers: DOI: 10.1016/j.cplett.2017.05.007
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Title: Chemical Physics Letters
  Abbreviation : Chem. Phys. Lett.
Source Genre: Journal
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Publ. Info: Amsterdam : North-Holland
Pages: - Volume / Issue: 683 Sequence Number: - Start / End Page: 160 - 165 Identifier: ISSN: 0009-2614
CoNE: /journals/resource/954925389241