English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Catalytic Asymmetric Thioacetalization of Aldehydes

Kim, J. H., Tap, A., Liu, L., & List, B. (2017). Catalytic Asymmetric Thioacetalization of Aldehydes. Synlett, 28(03), 333-336. doi:10.1055/s-0036-1588083.

Item is

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Kim, Ji Hye1, Author              
Tap, Aurélien1, Author              
Liu, Luping1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

Content

show
hide
Free keywords: thioacetals; imidodiphosphates; Brønsted acid catalysis
 Abstract: A catalytic enantioselective thioacetalization reaction has been developed. Various aldehydes react with unsymmetrical 1,3- or 1,2-dithiols to furnish chiral, enantioenriched thioacetals in excellent enantioselectivities upon treatment with a nitrated imidodiphosphoric acid catalyst. The transformation is assumed to proceed via a thionium ion intermediate.

Details

show
hide
Language(s): eng - English
 Dates: 2016-09-052016-10-042016-10-252017-02-14
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1055/s-0036-1588083
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Synlett
  Abbreviation : Synlett
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Stuttgart : Georg Thieme Verlag
Pages: - Volume / Issue: 28 (03) Sequence Number: - Start / End Page: 333 - 336 Identifier: ISSN: 0936-5214
CoNE: https://pure.mpg.de/cone/journals/resource/954925570856