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  Catalysis Meets Nonthermal Separation for the Production of (Alkyl)phenols and Hydrocarbons from Pyrolysis Oil

Cao, Z., Engelhardt, J., Dierks, M., Clough, M. T., Wang, G., Heracleous, E., et al. (2017). Catalysis Meets Nonthermal Separation for the Production of (Alkyl)phenols and Hydrocarbons from Pyrolysis Oil. Angewandte Chemie International Edition, 56(9), 2334-2339. doi:10.1002/anie.201610405.

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Cao, Z.1, Autor           
Engelhardt, Jan1, Autor           
Dierks, Michael1, Autor           
Clough, Matthew T.1, Autor           
Wang, Guanghui1, Autor           
Heracleous, Eleni2, 3, Autor
Lappas, Angelos2, 3, Autor
Rinaldi, Roberto4, 5, Autor           
Schüth, Ferdi1, Autor           
Affiliations:
1Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445589              
2Chemical Process Engineering Research Institute, Center for Research and Technology Hellas, Thessaloniki, Greece, ou_persistent22              
3School of Science & Technology, International Hellenic University, Thessaloniki, Greece, ou_persistent22              
4Department of Chemical Engineering, South Kensington Campus, Imperial College London, London, UK, ou_persistent22              
5Research Group Rinaldi, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445617              

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Schlagwörter: biomass, gas chromatography, hydrocarbons, molybdenum, phenols
 Zusammenfassung: A simple and efficient hydrodeoxygenation strategy is described to selectively generate and separate high-value alkylphenols from pyrolysis bio-oil, produced directly from lignocellulosic biomass. The overall process is efficient and only requires low pressures of hydrogen gas (5 bar). Initially, an investigation using model compounds indicates that MoCx/C is a promising catalyst for targeted hydrodeoxygenation, enabling selective retention of the desired Ar−OH substituents. By applying this procedure to pyrolysis bio-oil, the primary products (phenol/4-alkylphenols and hydrocarbons) are easily separable from each other by short-path column chromatography, serving as potential valuable feedstocks for industry. The strategy requires no prior fractionation of the lignocellulosic biomass, no further synthetic steps, and no input of additional (e.g., petrochemical) platform molecules.

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Sprache(n): eng - English
 Datum: 2017-02-142017-02-20
 Publikationsstatus: Erschienen
 Seiten: -
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 Inhaltsverzeichnis: -
 Art der Begutachtung: Expertenbegutachtung
 Identifikatoren: DOI: 10.1002/anie.201610405
BibTex Citekey: ANIE:ANIE201610405
 Art des Abschluß: -

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Titel: Angewandte Chemie International Edition
  Andere : Angew. Chem., Int. Ed.
  Andere : Angew. Chem. Int. Ed.
  Andere : Angewandte Chemie, International Edition
Genre der Quelle: Zeitschrift
 Urheber:
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Ort, Verlag, Ausgabe: Weinheim : Wiley-VCH
Seiten: - Band / Heft: 56 (9) Artikelnummer: - Start- / Endseite: 2334 - 2339 Identifikator: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851