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  Metallation of porphyrins in lipid monolayers at the air/water interface.

Loschek, R., & Möbius, D. (1988). Metallation of porphyrins in lipid monolayers at the air/water interface. Chemical Physics Letters, 151(1-2), 176-182. doi:10.1016/0009-2614(88)80091-5.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-42EF-0 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-42F1-8
Genre: Journal Article

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 Creators:
Loschek, R.1, Author              
Möbius, D.1, Author              
Affiliations:
1Research Group of Molecular Organized Systems, MPI for biophysical chemistry, Max Planck Society, ou_578548              

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 Abstract: Protonation and metallation equilibrium constants of two amphiphilic porphyrins in different lipid matrices have been determined at the air-water interface by means of reflection spectroscopy. Evidence for a dissociation mechanism of porphyrin metal complex formation is obtained from shifts of the protonation pKa and metallation pKc values upon variation of matrixand porphyrin.

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Language(s): eng - English
 Dates: 1988-10-07
 Publication Status: Published in print
 Pages: -
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 Table of Contents: -
 Rev. Method: Peer
 Identifiers: DOI: 10.1016/0009-2614(88)80091-5
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Title: Chemical Physics Letters
Source Genre: Journal
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Pages: - Volume / Issue: 151 (1-2) Sequence Number: - Start / End Page: 176 - 182 Identifier: -