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  Inside Back Cover: Structure and Fluxionality of B13+ Probed by Infrared Photodissociation Spectroscopy

Fagiani, M. R., Song, X., Petkov, P., Debnath, S., Gewinner, S., Schöllkopf, W., et al. (2017). Inside Back Cover: Structure and Fluxionality of B13+ Probed by Infrared Photodissociation Spectroscopy. Angewandte Chemie International Edition, 56(2), 655-655. doi:10.1002/anie.201610954.

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 Creators:
Fagiani, Matias Ruben1, 2, Author              
Song, Xiaowei1, 2, Author              
Petkov, Petko2, Author
Debnath, Sreekanta1, 2, Author              
Gewinner, Sandy1, Author              
Schöllkopf, Wieland1, Author              
Heine, Thomas2, Author
Fielicke, André3, Author
Asmis, Knut R.2, Author
Affiliations:
1Molecular Physics, Fritz Haber Institute, Max Planck Society, ou_634545              
2Wilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie, Universität Leipzig, ou_persistent22              
3Institut für Optik und Atomare Physik, Technische Universität Berlin, Hardenbergstraße 36, 10623 Berlin (Germany), ou_persistent22              

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 Abstract: The magic number boron cluster B13+ previously termed as a “molecular Wankel motor”, is predicted to exhibit an exceptional fluxionality already at low temperatures. In their Communication on page 505 ff., K. R. Asmis et al. spectroscopically confirm the structural assignment to a planar boron double wheel species and present the first experimental evidence for the quasi-rotation of the inner B3-ring using cryogenic ion vibrational spectroscopy of B13+ combined with density functional theory computations and Born–Oppenheimer molecular dynamics simulations.

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Language(s): eng - English
 Dates: 2016-12-072017-01-09
 Publication Status: Published in print
 Pages: 1
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201610954
 Degree: -

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Title: Angewandte Chemie International Edition
  Other : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: 1 Volume / Issue: 56 (2) Sequence Number: - Start / End Page: 655 - 655 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851