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  Laser mass spectrometric detection of AlH molecules as collision-free excimer laser photoproducts from aluminum alkyls.

Zhang, Y., & Stuke, M. (1988). Laser mass spectrometric detection of AlH molecules as collision-free excimer laser photoproducts from aluminum alkyls. Chemical Physics Letters, 149(3), 310-315. doi:10.1016/0009-2614(88)85032-2.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-4B99-4 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-4B9B-F
Genre: Journal Article

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 Creators:
Zhang, Y.1, Author              
Stuke, M.1, Author              
Affiliations:
1Abteilung Laserphysik, MPI for biophysical chemistry, Max Planck Society, ou_578547              

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 Abstract: Aluminum hydride molecules AlH are detected and identified by tunable dye-laser mass spectroscopy as collision-free UV excimer laser photoproducts of the Al alkyls TEA (triethylaluminum (C2H5)3Al) and TIBA (triisobutylaluminum (i-C4H9)3Al) at 248 and 193 nm. An internal energy distribution analysis of the photoproducts shows only minor vibrational excitation of ν″ = 1 and a Boltzmann-type rotational energy distribution with a temperature of about 0.03 eV, compared to the incoming photon energy of 5.0 or 6.42 eV.

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Language(s): eng - English
 Dates: 1988-08
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1016/0009-2614(88)85032-2
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Title: Chemical Physics Letters
Source Genre: Journal
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Publ. Info: -
Pages: - Volume / Issue: 149 (3) Sequence Number: - Start / End Page: 310 - 315 Identifier: -