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  Fluorine hyperfine interaction in aromatic anion radicals

Fischer, P. H. H., & Colpa, J. P. (1969). Fluorine hyperfine interaction in aromatic anion radicals. Zeitschrift für Naturforschung, A: Physical Sciences, 24(12), 1980-1988. doi:10.1515/zna-1969-1219.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-002D-61EA-4 Version Permalink: https://hdl.handle.net/21.11116/0000-000A-3AAE-2
Genre: Journal Article

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ZsNaturforschA_24_1969_1980.pdf (Any fulltext), 8MB
 
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 Creators:
Fischer, Peter H. H.1, Author           
Colpa, J. P., Author
Affiliations:
1Max Planck Institute for Medical Research, Max Planck Society, ou_1125545              

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 Abstract: The relation between the fluorine hyperfine splittings in about 20 fluorine substituted aromatic radicals and the π spin densities calculated according to McLachlans method is analysed with an expression of the type

aF = QFFF ρπFF + QFCC ρπCC + (QFFC + QFFC) ρπFC .

For the Q factors the following values are obtained:

QFFF =931 gauss; QFCC =86.6 gauss and (QFFC + QFFC) =345 gauss.

Two simpler expressions with one and two parameters respectively are also tested.

A theoretical estimate is made for the values of the Q factors and the results are compared with the values obtained semi-empirically.

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Language(s): eng - English
 Dates: 1969-08-052014-06-021969-12
 Publication Status: Issued
 Pages: 9
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1515/zna-1969-1219
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Title: Zeitschrift für Naturforschung, A: Physical Sciences
  Other : Z. Naturforsch., A: Phys. Sci.
Source Genre: Journal
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Publ. Info: Tübingen : Verlag der Zeitschrift für Naturforschung
Pages: - Volume / Issue: 24 (12) Sequence Number: - Start / End Page: 1980 - 1988 Identifier: ISSN: 1865-7109
CoNE: https://pure.mpg.de/cone/journals/resource/954928567579