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  Spin-rotation interaction and anisotropic chemical shift in 13CS2

Spiess, H. W., Schweitzer, D., Haeberlen, U., & Hausser, K. H. (1971). Spin-rotation interaction and anisotropic chemical shift in 13CS2. Journal of Magnetic Resonance, 5(1), 101-108. doi:10.1016/0022-2364(71)90068-0.

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JMagnReson_5_1971_101.pdf (Any fulltext), 444KB
 
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 Creators:
Spiess, Hans W.1, Author           
Schweitzer, Dieter2, Author           
Haeberlen, Ulrich3, Author           
Hausser, Karl H.2, Author           
Affiliations:
1Emeritus Group Spiess: Polymer Spectroscopy, MPI for Polymer Research, Max Planck Society, ou_1800296              
2Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497705              
3Research Group Prof. Dr. Haeberlen, Max Planck Institute for Medical Research, Max Planck Society, ou_1497739              

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 Abstract: The 13C nuclear spin-lattice relaxation time T1 was studied in liquid CS2 from −106°C to +35°C at resonance frequencies of 14, 30, and 62 MHz. The relaxation is caused by anisotropic chemical shift and spin-rotation interaction. It is shown that for linear molecules the spin-rotation constant C and the anisotropy of the chemical shift Δσ can be obtained from the relaxation rates without use of adjustable parameters. The analysis yields: C = -13.8 ± 1.4 kHz and Δσ = 438 ± 44 ppm.

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Language(s): eng - English
 Dates: 1971-02-011971-03-232004-07-011971-08
 Publication Status: Issued
 Pages: 8
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/0022-2364(71)90068-0
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Title: Journal of Magnetic Resonance
Source Genre: Journal
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Publ. Info: San Diego [etc.] : Academic Press
Pages: - Volume / Issue: 5 (1) Sequence Number: - Start / End Page: 101 - 108 Identifier: ISSN: 0022-2364
CoNE: https://pure.mpg.de/cone/journals/resource/954922651175_1