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  Towards longer-lived metal-to-ligand charge transfer states of iron(II) complexes: An N-heterocyclic carbene approach.

Liu, Y., Harlang, T., Canton, S. E., Chabera, P., Suarez-Alcantara, K., Fleckhaus, A., et al. (2013). Towards longer-lived metal-to-ligand charge transfer states of iron(II) complexes: An N-heterocyclic carbene approach. Chemical Communications, 49(57), 6412-6414. doi:10.1039/c3cc43833c.

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 Creators:
Liu, Y., Author
Harlang, T., Author
Canton, S. E.1, Author           
Chabera, P., Author
Suarez-Alcantara, K., Author
Fleckhaus, A., Author
Vithanage, D. A., Author
Goransson, E., Author
Corani, A., Author
Lomoth, R., Author
Sundstrom, V., Author
Warnmark, K., Author
Affiliations:
1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society, ou_578564              

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 Abstract: A 9 ps (MLCT)-M-3 lifetime was achieved by a Fe-II complex based on C(NHC)boolean AND N(py)boolean AND C(NHC) pincer ligands. This is the longest known so far for any kind of complexes of this abundant metal, and increased by almost two orders of magnitude compared to the reference Fe-II bis-terpyridine complex.

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Language(s): eng - English
 Dates: 2013-06-102013
 Publication Status: Issued
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/c3cc43833c
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Title: Chemical Communications
Source Genre: Journal
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Pages: - Volume / Issue: 49 (57) Sequence Number: - Start / End Page: 6412 - 6414 Identifier: -