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  High-Pressure NiAs-Type Modification of FeN

Clark, W. P., Steinberg, S., Dronskowski, R., McCammon, C., Kupenko, I., Bykov, M., et al. (2017). High-Pressure NiAs-Type Modification of FeN. Angewandte Chemie International Edition in English, 56(25), 7302-7306. doi:10.1002/anie.201702440.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-85AC-1 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-85B5-B
Genre: Journal Article

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 Creators:
Clark, William P.1, Author
Steinberg, Simon1, Author
Dronskowski, Richard1, Author
McCammon, Catherine1, Author
Kupenko, Ilya1, Author
Bykov, Maxim1, Author
Dubrovinsky, Leonid1, Author
Akselrud, Lev G.2, Author              
Schwarz, Ulrich3, Author              
Niewa, Rainer1, Author
Affiliations:
1External Organizations, ou_persistent22              
2Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
3Ulrich Schwarz, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863423              

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 Abstract: The combination of laser-heated diamond anvil cells and synchrotron Mossbauer source spectroscopy were used to investigate high-temperature high-pressure chemical reactions of iron and iron nitride Fe2N with nitrogen. At pressures between 10 and 45 GPa, significant magnetic hyperfine splitting indicated compound formation after annealing at 1300 K. Subsequent in situ X-ray diffraction reveals a new modification of FeN with NiAs-type crystal structure, as also rationalized by first-principles total-energy and chemical-bonding studies.

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Language(s): eng - English
 Dates: 2017-05-182017-05-18
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: ISI: 000402857800056
DOI: 10.1002/anie.201702440
 Degree: -

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Title: Angewandte Chemie International Edition in English
  Other : Angewandte Chemie, International Edition in English
  Other : Angew. Chem., Int. Ed. Engl.
  Other : Angew. Chem. Int. Ed. Engl.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 56 (25) Sequence Number: - Start / End Page: 7302 - 7306 Identifier: ISSN: 0570-0833
CoNE: /journals/resource/0570-0833