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  Experimental evidence of a dynamic Jahn-Teller effect in C+60.

Canton, S. E., Yencha, A. J., Kukk, E., Bozek, J. D., Lopes, M. C. A., Snell, G., et al. (2002). Experimental evidence of a dynamic Jahn-Teller effect in C+60. Physical Review Letters, 89(4): 045502. doi:10.1103/PhysRevLett.89.045502.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-002D-88DB-5 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-002D-88DC-3
Genre: Journal Article

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Canton, S. E.1, Author           
Yencha, A. J., Author
Kukk, E., Author
Bozek, J. D., Author
Lopes, M. C. A., Author
Snell, G., Author
Berrah, N., Author
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1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society, ou_578564              

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 Abstract: Detailed analysis of the highest occupied molecular orbital band shape in the photoelectron spectrum of gaseous C60 reveals a dynamic Jahn-Teller effect in the ground state of C+60. The direct observation of three tunneling states asserts a D3d geometry for the isolated cation, originating from a strong vibronic coupling. These results show that the ionic motion plays an important role in the electron-phonon interaction.

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Language(s): eng - English
 Dates: 2002-07-08
 Publication Status: Published online
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 Rev. Type: Peer
 Identifiers: DOI: 10.1103/PhysRevLett.89.045502
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Title: Physical Review Letters
Source Genre: Journal
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Pages: 4 Volume / Issue: 89 (4) Sequence Number: 045502 Start / End Page: - Identifier: -