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  Two Exceptional Homoleptic Iron(IV) Tetraalkyl Complexes

Casitas, A., Rees, J. A., Goddard, R., Bill, E., DeBeer, S., & Fürstner, A. (2017). Two Exceptional Homoleptic Iron(IV) Tetraalkyl Complexes. Angewandte Chemie International Edition, 56(34), 10108-10113. doi:10.1002/anie.201612299.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-C624-F Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-C625-D
Genre: Journal Article

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 Creators:
Casitas, Alicia1, Author              
Rees, Julian A.2, 3, Author
Goddard, Richard4, Author              
Bill, Eckhard2, Author
DeBeer, Serena2, 5, Author
Fürstner, Alois1, Author              
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
2Max-Planck-Institut für Chemische Energiekonversion, Mülheim/Ruhr, Germany, ou_persistent22              
3Department of Chemistry, University of Washington, Seattle, WA, USA, ou_persistent22              
4Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              
5Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY, USA, ou_persistent22              

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Free keywords: hydride elimination; iron; London dispersive forces; transition metal complexes
 Abstract: The formation of the high-valent iron complex [Fe(cyclohexyl)4] from FeII under reducing conditions is best explained by disproportionation of a transient organoiron intermediate which is driven by dispersive forces between the cyclohexyl ligands and the formation of short and strong Fe−C bonds. The (meta)stability of this diamagnetic complex (S=0) is striking if one considers that it has empty d-orbitals at its disposal and contains, at the same time, no less than twenty H-atoms available for either α- or β-hydride elimination.

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Language(s): eng - English
 Dates: 2017-01-302016-12-192017-03-022017-08-17
 Publication Status: Published in print
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Identifiers: DOI: 10.1002/anie.201612299
 Degree: -

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Title: Angewandte Chemie International Edition
  Other : Angew. Chem., Int. Ed.
  Other : Angew. Chem. Int. Ed.
  Other : Angewandte Chemie, International Edition
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 56 (34) Sequence Number: - Start / End Page: 10108 - 10113 Identifier: ISSN: 1433-7851
CoNE: /journals/resource/1433-7851