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  Catalytic role of vacancy diffusion in ceria supported atomic gold catalyst

Han, Z.-K., Wang, Y., & Gao, Y. (2017). Catalytic role of vacancy diffusion in ceria supported atomic gold catalyst. Chemical Communications, 53(65), 9125-9128. doi:10.1039/C7CC04440B.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-002D-CF37-8 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-002D-E634-7
Genre: Journal Article

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c7cc04440b.pdf (Publisher version), 3MB
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 Creators:
Han, Zhong-Kang1, 2, Author
Wang, Yanggang3, Author           
Gao, Yi1, 4, Author
Affiliations:
1Division of Interfacial Water and Key Laboratory of Interfacial Physics and Technology, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, 201800 China, ou_persistent22              
2University of Chinese Academy of Sciences, Beijing, 100049 China, ou_persistent22              
3Theory, Fritz Haber Institute, Max Planck Society, ou_634547              
4Shanghai Science Research Center, Chinese Academy of Sciences, Shanghai, 201204 China, ou_persistent22              

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 Abstract: Dynamics of intrinsic defects are considered fundamental in the chemistry of reducible oxides, and their effect on catalytic reactions have been rarely reported. Herein, we propose a new Ov diffusion assisted Langmuir–Hinshelwood mechanism for CO oxidation, which may largely account for the origin of high reactivity of supported atomic gold catalysts.

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Language(s): eng - English
 Dates: 2017-06-082017-07-172017-07-172017-08-21
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/C7CC04440B
 Degree: -

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Title: Chemical Communications
  Other : Chem. Commun.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: 4 Volume / Issue: 53 (65) Sequence Number: - Start / End Page: 9125 - 9128 Identifier: ISSN: 1359-7345
CoNE: https://pure.mpg.de/cone/journals/resource/954928495413