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  Synthesis of methyl 4-dihydrotrisporate B and methyl trisporate B, morphogenetic factors of Zygomycetes fungi

Nakamura, Y., Paetz, C., & Boland, W. (2018). Synthesis of methyl 4-dihydrotrisporate B and methyl trisporate B, morphogenetic factors of Zygomycetes fungi. Zeitschrift für Naturforschung, C: Journal of Biosciences, 73(1), 59-66. doi:10.1515/znc-2017-0148.

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BOL686s1.pdf (Supplementary material), 519KB
 
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 Creators:
Nakamura, Yoko1, Author              
Paetz, Christian2, Author              
Boland, Wilhelm1, Author              
Affiliations:
1Department of Bioorganic Chemistry, Prof. Dr. W. Boland, MPI for Chemical Ecology, Max Planck Society, ou_24028              
2Research Group Biosynthesis / NMR, MPI for Chemical Ecology, Max Planck Society, ou_421898              

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 Abstract: (9Z)-Methyl 4-dihydrotrisporate B and (9Z)- methyl trisporate B, pheromones of Zygomycetes fungi, have been synthesized using Stille cross-coupling from previously described cyclohexenone precursors. Conducting the coupling without protection groups allowed for a short and stereospecific synthesis route of the late trisporoids. Stability studies for both the compounds revealed (9Z)-methyl trisporate B to be very unstable against UV irradiation.

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 Dates: 2017-10-122017-11-212018-01
 Publication Status: Published in print
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 Identifiers: Other: BOL686
DOI: 10.1515/znc-2017-0148
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Title: Zeitschrift für Naturforschung, C: Journal of Biosciences
  Abbreviation : Z. Naturforsch., C: J. Biosci.
Source Genre: Journal
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Publ. Info: Berlin : Walter de Gruyter GmbH
Pages: - Volume / Issue: 73 (1) Sequence Number: - Start / End Page: 59 - 66 Identifier: ISSN: 1865-7125
CoNE: https://pure.mpg.de/cone/journals/resource/954927655916_1