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  Organometallic rubidium and cesium compounds of the 5,6;11,12-di-o-phenylene-tetracene dianion

Wombacher, T., Goddard, R., Lehmann, C. W., & Schneider, J. J. (2017). Organometallic rubidium and cesium compounds of the 5,6;11,12-di-o-phenylene-tetracene dianion. Chemical Communications, 53(52), 7030-7033. doi:10.1039/c7cc02320k.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-002E-318E-2 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-1F0F-8
Genre: Journal Article

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 Creators:
Wombacher, Tobias1, Author
Goddard, Richard2, Author           
Lehmann, Christian W.2, Author           
Schneider, Jörg J.1, Author
Affiliations:
1Fachbereich Chemie, Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Alarich-Weiss Str. 12, 64287 Darmstadt, Germany, ou_persistent22              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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 Abstract: Twofold reduction of the title molecule 5,6; 11,12-di-o-phenylenetetracene (DOPT) with an excess of metallic rubidium and cesium in the presence of strongly coordinating ethers like 18-crown-6-ether (18C6) and tetraglyme results in the formation of the first Rb(I) triple-decker complex and the first Cs(I) coordination polymer of the so far only sparsely studied polyaromatic planar hydrocarbon DOPT. Both compounds are extremely sensitive towards air and water in solution as well as in the solid state. Both compounds exhibit isomerism within their crystal lattices.

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Language(s): eng - English
 Dates: 2017-03-272017-05-182017-06-142017-07-04
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/c7cc02320k
 Degree: -

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Title: Chemical Communications
  Abbreviation : Chem. Commun.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 53 (52) Sequence Number: - Start / End Page: 7030 - 7033 Identifier: ISSN: 1359-7345
CoNE: https://pure.mpg.de/cone/journals/resource/954928495413