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  Synthesis of Metal Sulfides from a Deep Eutectic Solvent Precursor (DESP)

Zhang, T., Doert, T., & Ruck, M. (2017). Synthesis of Metal Sulfides from a Deep Eutectic Solvent Precursor (DESP). Zeitschrift für anorganische und allgemeine Chemie, 643, 1913-1919. doi:10.1002/zaac.201700206.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002E-A002-9 Version Permalink: http://hdl.handle.net/21.11116/0000-0001-25B1-D
Genre: Journal Article

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 Creators:
Zhang, Tao1, Author
Doert, Thomas1, Author
Ruck, Michael2, Author              
Affiliations:
1External Organizations, ou_persistent22              
2Michael Ruck, Max Planck Fellow, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863444              

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 Abstract: Recently, deep eutectic solvents (DESs) have received great interest as sustainable reaction media for nanoscale and functional materials. We report on a new choline chloride (ChCl) and thioacetamide (TAA) based DES for the synthesis of a series of binary metal sulfides including Sb2S3, Bi2S3, PbS, CuS, Ag2S, ZnS, and CdS. In these reactions, the ChCl/TAA based DES serves as all-in-one reactant, solvent, and template or deep eutectic solvent precursor (DESP). The reaction is supposed to proceed in two steps. A metal-DES complex is first generated by adding the respective metal salts to the DES solution at a relatively low temperature. Then the metal-DES complex decomposes to form the final metal sulfides products upon heating. This method provides a simple reaction system and a general strategy to synthesize metal sulfides. Some unique shaped products, such as Sb2S3 plates agglomerated by rod-like particles, hexagonal CuS single crystals, and three-dimensional hierarchical ZnS microspheres, are obtained via this method and the sizes and shapes of obtained samples can to some extent be controlled by temperature or reactant concentrations.

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Language(s): eng - English
 Dates: 2017-09-192017-09-19
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: DOI: 10.1002/zaac.201700206
 Degree: -

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Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : Journal of Inorganic and General Chemistry
  Other : J. Inorg. Gen Chem.
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
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Publ. Info: Leipzig, Weinheim : Verlag Johann Ambrosius Barth / Wiley-VCH
Pages: - Volume / Issue: 643 Sequence Number: - Start / End Page: 1913 - 1919 Identifier: Other: 1521-3749
ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895