English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
 
 
DownloadE-Mail
  Comparative Study of Potentially Jeff=0 Ground State Iridium(V) in SrLaNiIrO6, SrLaMgIrO6, and SrLaZnIrO6

Wolff, K. K., Agrestini, S., Tanaka, A., Jansen, M., & Tjeng, L. H. (2017). Comparative Study of Potentially Jeff=0 Ground State Iridium(V) in SrLaNiIrO6, SrLaMgIrO6, and SrLaZnIrO6. Zeitschrift für anorganische und allgemeine Chemie, 643, 2095-2101. doi:10.1002/zaac.201700386.

Item is

Basic

show hide
Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002E-A010-9 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002E-A02E-9
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Wolff, Klaus K.1, Author              
Agrestini, Stefano2, Author              
Tanaka, Arata3, Author
Jansen, Martin1, Author              
Tjeng, Liu Hao4, Author              
Affiliations:
1Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863425              
2Stefano Agrestini, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863459              
3External Organizations, ou_persistent22              
4Liu Hao Tjeng, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863452              

Content

show
hide
Free keywords: -
 Abstract: A series of polycrystalline double perovskites SrLaBIrO6 (B = Ni, Mg, Zn) containing Ir5+ (5d(4)) was synthesized by solid state reactions, and structural, magnetic and electronic properties were investigated. The isotypic fully ordered double perovskites crystallize in space group P2(1)/n and show semiconducting behavior with estimated bandgaps of approximately 0.2 eV for SrLaNiIrO6 and SrLaZnIrO6, and 0.4 eV for SrLaMgIrO6. SrLaNiIrO6 is an antiferromagnet with a Neel temperature of 74 K ((eff) = 3.3 (B), (W) = -90 K), whereas SrLaMgIrO6 and SrLaZnIrO6 are weakly paramagnetic. All title compounds exhibit a temperature-independent contribution to the measured magnetic susceptibility, which supports the notion for a van-Vleck-type response originating from the Ir5+ (5d(4), J(eff) = 0) ions.

Details

show
hide
Language(s): eng - English
 Dates: 2017-11-272017-11-27
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: DOI: 10.1002/zaac.201700386
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : Journal of Inorganic and General Chemistry
  Other : J. Inorg. Gen Chem.
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Leipzig, Weinheim : Verlag Johann Ambrosius Barth / Wiley-VCH
Pages: - Volume / Issue: 643 Sequence Number: - Start / End Page: 2095 - 2101 Identifier: Other: 1521-3749
ISSN: 0044-2313
CoNE: /journals/resource/954925453895