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  Ligand effects of NHC–iridium catalysts for signal amplification by reversible exchange (SABRE)

van Weerdenburg, B. J. A., Glöggler, S., Eshuis, N., Engwerda, A. H. J. (., Smits, J. M. M., de Gelder, R., et al. (2013). Ligand effects of NHC–iridium catalysts for signal amplification by reversible exchange (SABRE). Chemical Communications, 49(67), 7388-7390. doi:10.1039/C3CC43423K.

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 Creators:
van Weerdenburg, B. J. A., Author
Glöggler, S.1, Author           
Eshuis, N., Author
Engwerda, A. H. J. (Ton), Author
Smits, J. M. M., Author
de Gelder, R., Author
Appelt, S., Author
Wymenga, S. S., Author
Tessari, M., Author
Feiters, M. C., Author
Blümich, B., Author
Rutjes, F.P. J. T., Author
Affiliations:
1Research Group of NMR Signal Enhancement, MPI for Biophysical Chemistry, Max Planck Society, ou_2396691              

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 Abstract: SABRE hyperpolarizes substrates by polarization transfer from para-hydrogen in a metal complex. We have measured the signal enhancement of pyridine and its exchange rate in various [Ir(NHC)(Py)3(H)2]+ complexes to gain insight into their dependence on the N-Heterocyclic Carbene (NHC) ligand's steric and electronic properties.

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Language(s): eng - English
 Dates: 2013-06-272013
 Publication Status: Issued
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 Rev. Type: Peer
 Identifiers: DOI: 10.1039/C3CC43423K
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Title: Chemical Communications
Source Genre: Journal
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Pages: - Volume / Issue: 49 (67) Sequence Number: - Start / End Page: 7388 - 7390 Identifier: -