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  Cooperative Formation of Long-Range Ordering in Water Ad-layers on Fe3O4(111) Surfaces

Mirabella, F., Zaki, E., Ivars Barcelo, F., Li, X., Paier, J., Sauer, J., et al. (2018). Cooperative Formation of Long-Range Ordering in Water Ad-layers on Fe3O4(111) Surfaces. Angewandte Chemie International Edition, 57(5), 1409-1413. doi:10.1002/anie.201711890.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0000-3F85-4 Version Permalink: https://hdl.handle.net/21.11116/0000-0000-3F99-E
Genre: Journal Article

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2018
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 Creators:
Mirabella, Francesca1, Author           
Zaki, Eman1, Author           
Ivars Barcelo, Francisco1, Author           
Li, Xiaoke2, Author
Paier, Joachim2, Author
Sauer, Joachim2, Author
Shaikhutdinov, Shamil K.1, Author           
Freund, Hans-Joachim1, Author           
Affiliations:
1Chemical Physics, Fritz Haber Institute, Max Planck Society, ou_24022              
2Institut für Chemie, Humboldt Universität zu Berlin , 10099 Berlin (Germany), ou_persistent22              

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 Abstract: The initial stages of water adsorption on magnetite Fe3O4(111) surface and the atomic structure of the water/oxide interface remain controversial. Herein, we provide experimental results obtained by infrared reflection–absorption spectroscopy (IRAS) and temperature-programmed desorption (TPD), corroborated by density functional theory (DFT) calculations showing that water readily dissociates on Fetet sites to form two hydroxo species. These act as an anchor for water molecules to form a dimer complex which self-assembles into an ordered (2×2) structure. Water ad-layer ordering is rationalized in terms of a cooperative effect induced by a hydrogen-bonding network.

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Language(s): eng - English
 Dates: 2017-11-202017-12-042018-01-222018-01-26
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201711890
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Title: Angewandte Chemie International Edition
  Other : Angew. Chem., Int. Ed.
  Other : Angew. Chem. Int. Ed.
  Other : Angewandte Chemie, International Edition
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: 5 Volume / Issue: 57 (5) Sequence Number: - Start / End Page: 1409 - 1413 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851