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  The Catalytic Asymmetric Mukaiyama–Michael Reaction of Silyl Ketene Acetals with α,β-Unsaturated Methyl Esters

Gatzenmeier, T., Kaib, P. S. J., Lingnau, J. B., Goddard, R., & List, B. (2018). The Catalytic Asymmetric Mukaiyama–Michael Reaction of Silyl Ketene Acetals with α,β-Unsaturated Methyl Esters. Angewandte Chemie International Edition, 57(9), 2464-2468. doi:10.1002/anie.201712088.

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Gatzenmeier, Kaib, Lingnau, Goddard, List 2018.pdf (Postprint), 689KB
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Gatzenmeier, Kaib, Lingnau, Goddard, List 2018.pdf
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 Creators:
Gatzenmeier, Tim1, Author              
Kaib, Philip S. J.1, Author              
Lingnau, Julia B.2, Author              
Goddard, Richard3, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              
2Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445623              
3Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Free keywords: Brønsted acids; cinnamates; Mukaiyama–Michael reaction; organocatalysis; silyl ketene acetals
 Abstract: α,β-Unsaturated esters are readily available but challenging substrates to activate in asymmetric catalysis. We now describe an efficient, general, and highly enantioselective Mukaiyama–Michael reaction of silyl ketene acetals with α,β-unsaturated methyl esters that is catalyzed by a silylium imidodiphosphorimidate (IDPi) Lewis acid.

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Language(s): eng - English
 Dates: 2017-11-242017-12-122018-02-23
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201712088
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 57 (9) Sequence Number: - Start / End Page: 2464 - 2468 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851