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  Di–tert–butyl N,N-diethylphosphoramidite as an Air Stable Ligand for Suzuki-Miyaura and Buchwald-Hartwig Reactions

Ilie, A., Roiban, G.-D., & Reetz, M. T. (2017). Di–tert–butyl N,N-diethylphosphoramidite as an Air Stable Ligand for Suzuki-Miyaura and Buchwald-Hartwig Reactions. ChemistrySelect, 2(4), 1392-1397. doi:10.1002/slct.201700086.

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Genre: Journal Article

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 Creators:
Ilie, Adriana1, 2, Author              
Roiban, Georghe-Doru1, 2, 3, Author              
Reetz, Manfred T.1, 2, Author              
Affiliations:
1Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445588              
2Philipps-Universität, Fachbereich Chemie, Marburg, Germany, ou_persistent22              
3GlaxoSmithKline plc, Medicines Research Centre, Hertfordshire, U.K, ou_persistent22              

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Free keywords: animation; homogeneous catalysis; P ligand; palladium; Suzuki cross-coupling
 Abstract: We describe herein an air stable phosphorus ligand for both Suzuki-Miyaura and Buchwald-Hartwig palladium-catalyzed cross coupling reactions. The versatility of the Pd(dba)2-di-tert-butyl N,N-diethylphosphoramidite catalytic system is demonstrated for a variety of aryl and heteroaryl halides. This ligand is "bench stable" which allows easy catalyst preparation. Moreover, even at low catalyst loadings (0.5 %), excellent yields are usually achieved.

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 Dates: 2017-01-162017-01-192017-02-01
 Publication Status: Published online
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/slct.201700086
 Degree: -

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Title: ChemistrySelect
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 2 (4) Sequence Number: - Start / End Page: 1392 - 1397 Identifier: Other: 2365-6549
CoNE: https://pure.mpg.de/cone/journals/resource/2365-6549