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  Synthesis, structure and stability of a chiral imine-based Schiff-based ligand derived from L-glutamic acid and its [Cu4] complex

Muche, S., Levacheva, I., Samsonova, O., Biernasiuk, A., Malm, A., Lonsdale, R., et al. (2017). Synthesis, structure and stability of a chiral imine-based Schiff-based ligand derived from L-glutamic acid and its [Cu4] complex. Journal of Molecular Structure, 1127, 231-236. doi:10.1016/j.molstruc.2016.07.100.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0000-FFD8-E Version Permalink: https://hdl.handle.net/21.11116/0000-0000-FFD9-D
Genre: Journal Article

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 Creators:
Muche, Simon1, Author
Levacheva, Irina2, Author
Samsonova, Olga2, Author
Biernasiuk, Anna3, Author
Malm, Anna3, Author
Lonsdale, Richard1, 4, Author           
Popiołek, Łukasz5, Author
Bakowsky, Udo2, Author
Hołynska, Małgorzata1, Author
Affiliations:
1Fachbereich Chemie und Wissenschaftliches Zentrum für Materialwissenschaften, Philipps-Universität Marburg, Hans-Meerweinstraße, D-35043 Marburg, Germany, ou_persistent22              
2Institut für Pharmazeutische Technologie und Biopharmazie, Medical University, Philipps-Universität Marburg, Ketzerbach 63, D-35032, Marburg, Germany, ou_persistent22              
3Department of Pharmaceutical Microbiology, Medical University, Chodzki 1, 20-093, Lublin, Poland, ou_persistent22              
4Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445588              
5Department of Organic Chemistry, Medical University of Lublin, Chodzki 4A, 20-093, Lublin, Poland, ou_persistent22              

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Free keywords: Copper (II); Schiff-base; Stability; Crystal structure
 Abstract: Studies of the stability of a ligand derived from L-glutamic acid and ortho-vanillin and its new [Cu4] complex are presented. The [Cu4] complex contains a heterocubane [CuII4O4] core and pendant carboxylic groups increasing its solubility in water, also under basic conditions. The stability of the complex in different solvents is confirmed with ESI-MS studies and such experiments as successful recrystallization. The complex is stable also under physiological conditions whereas the ligand is partly decomposed to L-glutamic acid and ortho-vanillin.

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Language(s): eng - English
 Dates: 2016-06-192016-07-252016-07-272017-01-05
 Publication Status: Issued
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/j.molstruc.2016.07.100
 Degree: -

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Title: Journal of Molecular Structure
Source Genre: Journal
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Publ. Info: Amsterdam : Elsevier
Pages: - Volume / Issue: 1127 Sequence Number: - Start / End Page: 231 - 236 Identifier: ISSN: 0022-2860
CoNE: https://pure.mpg.de/cone/journals/resource/954925415947