English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Cyclopentadienone iron complexes as efficient and selective catalysts for the electroreduction of CO2 to CO

Rosas-Hernández, A., Junge, H., Beller, M., Roemelt, M., & Francke, R. (2017). Cyclopentadienone iron complexes as efficient and selective catalysts for the electroreduction of CO2 to CO. Catalysis Science & Technology, 7(2), 459-465. doi: 10.1039/C6CY02352E.

Item is

Basic

show hide
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Rosas-Hernández , Alonso1, Author
Junge, Henrik1, Author
Beller, Matthias1, Author
Roemelt, Michael2, 3, Author              
Francke, Robert4, Author
Affiliations:
1Leibniz Institute for Catalysis, Albert-Einstein-Str. 29a, 18059 Rostock, Germany , ou_persistent22              
2Lehrstuhl für Theoretische Chemie, Ruhr-University Bochum, 44780 Bochum, Germany, ou_persistent22              
3Research Group Roemelt, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_3018043              
4Institute of Chemistry, Rostock University, Albert-Einstein-Str. 3a, 18059 Rostock, Germany , ou_persistent22              

Content

show
hide
Free keywords: -
 Abstract: Herein, we report the use of molecularly-defined cyclopentadienone iron(0) complexes as selective and efficient catalysts for the electrochemical conversion of CO2 to CO in the absence of Brønsted acids. Under optimized conditions, carbon monoxide was selectively formed with a faradaic efficiency of 96%. Cooperation between the metal center and ligand is crucial for the catalytic activity of the system.

Details

show
hide
Language(s): eng - English
 Dates: 2016-11-092016-12-212017-01-022017-01-21
 Publication Status: Published in print
 Pages: 7
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/C6CY02352E
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Catalysis Science & Technology
  Other : Catal. Sci. Technol.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 7 (2) Sequence Number: - Start / End Page: 459 - 465 Identifier: ISSN: 2044-4753
CoNE: https://pure.mpg.de/cone/journals/resource/2044-4753