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  Ether Synthesis through Reductive Cross-Coupling of Ketones with Alcohols Using Me2SiHCl as both Reductant and Lewis Acid

Lee, Y. H., & Morandi, B. (2017). Ether Synthesis through Reductive Cross-Coupling of Ketones with Alcohols Using Me2SiHCl as both Reductant and Lewis Acid. Synlett, 28(18), 2425-2428. doi:10.1055/s-0036-1590838.

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Genre: Journal Article

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 Creators:
Lee, Yong Ho1, Author
Morandi, Bill1, Author           
Affiliations:
1Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040309              

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Free keywords: silanes; Lewis acid; ketones; alcohols; ethers; reductive coupling
 Abstract: We report that a Lewis acidic silane, Me2SiHCl, can mediate the direct cross-coupling of a wide range of carbonyl compounds with alcohols to form dialkyl ethers. The reaction is operationally simple, tolerates a range of polar functional groups, can be utilized to make sterically hindered ethers, and is extendable to sulfur and nitrogen nucleo­philes.

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Language(s): eng - English
 Dates: 2017-05-052017-06-202017-07-202017-11-28
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1055/s-0036-1590838
 Degree: -

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Title: Synlett
  Other : Synlett
Source Genre: Journal
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Publ. Info: Stuttgart : Georg-Thieme-Verlag
Pages: - Volume / Issue: 28 (18) Sequence Number: - Start / End Page: 2425 - 2428 Identifier: ISSN: 0936-5214
CoNE: https://pure.mpg.de/cone/journals/resource/954925570856