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  Stereoselective synthesis and hormonal activity of novel dafachronic acids and naturally occurring steroids isolated from corals.

Saini, R., Boland, S., Kataeva, O., Schmidt, A. W., Kurzchalia, T. V., & Knölker, H.-J. (2012). Stereoselective synthesis and hormonal activity of novel dafachronic acids and naturally occurring steroids isolated from corals. Organic & Biomolecular Chemistry, 10(21), 4159-4163.

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 Creators:
Saini, Ratni, Author
Boland, Sebastian1, Author           
Kataeva, Olga, Author
Schmidt, Arndt W, Author
Kurzchalia, Teymuras V.1, Author           
Knölker, Hans-Joachim, Author
Affiliations:
1Max Planck Institute of Molecular Cell Biology and Genetics, Max Planck Society, ou_2340692              

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 Abstract: A stereoselective synthesis of (25S)-Δ(1)-, (25S)-Δ(1,4)-, (25S)-Δ(1,7)-, (25S)-Δ(8(14))-, (25S)-Δ(4,6,8(14))-dafachronic acid, methyl (25S)-Δ(1,4)-dafachronate and (25S)-5α-hydroxy-3,6-dioxocholest-7-en-26-oic acid is described. (25S)-Δ(1,4)-Dafachronic acid and its methyl ester are natural products isolated from corals and have been obtained by synthesis for the first time. (25S)-5α-Hydroxy-3,6-dioxocholest-7-en-26-oic acid represents a promising synthetic precursor for cytotoxic marine steroids.

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 Dates: 2012
 Publication Status: Issued
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 Identifiers: eDoc: 645243
Other: 4974
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Title: Organic & Biomolecular Chemistry
Source Genre: Journal
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Pages: - Volume / Issue: 10 (21) Sequence Number: - Start / End Page: 4159 - 4163 Identifier: -