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  Monitoring the formation of PtNi nanoalloys supported on hollow graphitic spheres using in situ pair distribution function analysis

Ortatatlı, Ş., Knossalla, J., Schüth, F., & Weidenthaler, C. (2018). Monitoring the formation of PtNi nanoalloys supported on hollow graphitic spheres using in situ pair distribution function analysis. Physical Chemistry Chemical Physics, 20(13), 8466-8474. doi:10.1039/C7CP07840D.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0001-2AD3-2 Version Permalink: http://hdl.handle.net/21.11116/0000-0007-5D20-D
Genre: Journal Article

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 Creators:
Ortatatlı, Şeyma1, Author              
Knossalla, Johannes2, Author              
Schüth, Ferdi2, Author              
Weidenthaler, Claudia1, Author              
Affiliations:
1Research Group Weidenthaler, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1950291              
2Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445589              

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 Abstract: This article aims to address the formation and the structural disordering/ordering phenomena of PtNi nanoalloys supported on hollow graphitic spheres (HGSs) using pair distribution function (PDF) analysis under ex situ/in situ data collection conditions. Starting from small nanoparticles (10-15 Å in diameter) embedded in HGSs, structural changes were monitored during stepwise heating and cooling of the sample using in situ PDF analysis. In order to evaluate the conventional synthesis route for the production of PtNi nanoalloys supported on HGSs, ex situ PDF experiments were performed before and after heat treatment in a furnace. The studies demonstrate that the local structure of the in situ synthesised PtNi nanoalloy differs from its ex situ synthesised counterpart. A partially ordered PtNi nanoalloy was obtained during the stepwise in situ cooling of the precursor, whereas the conventional ex situ synthesis route did not lead to the formation of an ordered crystal structure. In this study we could show that rapid heating and cooling results in a disordered PtNi alloy whereas slow heating and cooling leads to disorder-order transitions in PtNi.

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Language(s): eng - English
 Dates: 2017-11-212018-01-032018-01-192018-04-07
 Publication Status: Published in print
 Pages: 9
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/C7CP07840D
 Degree: -

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Title: Physical Chemistry Chemical Physics
  Abbreviation : Phys. Chem. Chem. Phys.
Source Genre: Journal
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Publ. Info: Cambridge, England : Royal Society of Chemistry
Pages: - Volume / Issue: 20 (13) Sequence Number: - Start / End Page: 8466 - 8474 Identifier: ISSN: 1463-9076
CoNE: https://pure.mpg.de/cone/journals/resource/954925272413_1