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  Stability of the Zwitterionic Liquid Butyl-Methyl-Imidazol-2-ylidene Borane

Tröger-Müller, S., Antonietti, M., & Liedel, C. (2018). Stability of the Zwitterionic Liquid Butyl-Methyl-Imidazol-2-ylidene Borane. Physical Chemistry Chemical Physics, 20(16), 11437-11443. doi:10.1039/C8CP00311D.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0001-1D18-5 Version Permalink: http://hdl.handle.net/21.11116/0000-0001-4746-1
Genre: Journal Article

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 Creators:
Tröger-Müller, Steffen1, Author              
Antonietti, Markus2, Author              
Liedel, Clemens1, Author              
Affiliations:
1Clemens Liedel, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_2288694              
2Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863321              

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Free keywords: Open Access
 Abstract: Modification of the C2 position of the standard 1-butyl-3-methyl imidazolium cation by a borohydride group leads to a zwitterionic liquid (ZIL). The resulting imidazol-2-ylidene borane ZIL is liquid at room temperature. Dynamic viscosity as well as thermal and electrochemical stability are investigated. Thermal decomposition follows a similar pathway as in comparable imidazolium ionic liquids. The surprisingly low viscosity and good reductive stability make it a promising candidate for electrochemical applications.

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 Dates: 2018-03-272018-04-28
 Publication Status: Published in print
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 Identifiers: DOI: 10.1039/C8CP00311D
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Title: Physical Chemistry Chemical Physics
  Abbreviation : Phys. Chem. Chem. Phys.
Source Genre: Journal
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Publ. Info: Cambridge, England : Royal Society of Chemistry
Pages: - Volume / Issue: 20 (16) Sequence Number: - Start / End Page: 11437 - 11443 Identifier: ISSN: 1463-9076