Deutsch
 
Hilfe Datenschutzhinweis Impressum
  DetailsucheBrowse

Datensatz

DATENSATZ AKTIONENEXPORT
  Crystal Growth Via the Gas Phase by Chemical Vapor Transport Reactions

Binnewies, M., Glaum, R., Schmidt, M., & Schmidt, P. (2017). Crystal Growth Via the Gas Phase by Chemical Vapor Transport Reactions. In R. Dronskowski (Ed.), Handbook of Solid State Chemistry (pp. 351-374). Weinheim: Wiley-VCH. doi:10.1002/9783527691036.hsscvol2020.

Item is

Externe Referenzen

einblenden:

Urheber

einblenden:
ausblenden:
 Urheber:
Binnewies, Michael1, Autor           
Glaum, Robert2, Autor
Schmidt, Marcus3, Autor           
Schmidt, Peer2, Autor
Affiliations:
1Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
2External Organizations, ou_persistent22              
3Marcus Schmidt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863415              

Inhalt

einblenden:
ausblenden:
Schlagwörter: co‐operative transport model, condensed phase, crystal growth, gas phase solubility, hydrogen chloride, nonstationary chemical vapor transport experiment, tellurium(IV) chloride, transport agent
 Zusammenfassung: Abstract By means of chemical vapor transport reactions (CVT) a variety of solid‐state compounds can be prepared, mostly as impurity free single crystals. Representatives are well‐established for elements, intermetallics, halides, oxides, sulphides, selenides, tellurides, pnictides, and so on. The fundamental thermodynamic principles of CVT reactions are discussed for both single equilibrium reactions (Schaefer model) and more complex reaction mechanisms using the term “gas phase solubility.” Different working techniques for realization of vapor transport experiments are described in detail: application of suitable ampoule materials, furnace assembly, handling of different transport agents, calculation of vapor pressure, experimental procedure. The characteristic vapor transport behavior is described for selected representatives of above‐mentioned classes of solids. Accordingly, some information is given concerning the choice of appropriate transport agent, the evaluation of transport direction, and the viable transport conditions. The simplified deduction or estimation of transport conditions for new compounds of related chemical composition or similar chemical behavior is discussed for the different substance classes. At least, complex thermodynamic modeling of CVT reactions applying the CalPhaD method using freeware is introduced.

Details

einblenden:
ausblenden:
Sprache(n): eng - English
 Datum: 2017-06-012017-06-01
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: -
 Identifikatoren: DOI: 10.1002/9783527691036.hsscvol2020
 Art des Abschluß: -

Veranstaltung

einblenden:

Entscheidung

einblenden:

Projektinformation

einblenden:

Quelle 1

einblenden:
ausblenden:
Titel: Handbook of Solid State Chemistry
Genre der Quelle: Buch
 Urheber:
Dronskowski, Richard, Herausgeber
Affiliations:
-
Ort, Verlag, Ausgabe: Weinheim : Wiley-VCH
Seiten: XXIV, 616 Band / Heft: 2 Artikelnummer: - Start- / Endseite: 351 - 374 Identifikator: ISBN: 978-3-527-69103-6