English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Crystal Growth Via the Gas Phase by Chemical Vapor Transport Reactions

Binnewies, M., Glaum, R., Schmidt, M., & Schmidt, P. (2017). Crystal Growth Via the Gas Phase by Chemical Vapor Transport Reactions. In R. Dronskowski (Ed.), Handbook of Solid State Chemistry (pp. 351-374). Weinheim: Wiley-VCH. doi:10.1002/9783527691036.hsscvol2020.

Item is

Basic

show hide
Item Permalink: http://hdl.handle.net/21.11116/0000-0001-3B8E-E Version Permalink: http://hdl.handle.net/21.11116/0000-0001-3E9F-8
Genre: Book Chapter

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Binnewies, Michael1, Author              
Glaum, Robert2, Author
Schmidt, Marcus3, Author              
Schmidt, Peer2, Author
Affiliations:
1Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
2External Organizations, ou_persistent22              
3Marcus Schmidt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863415              

Content

show
hide
Free keywords: co‐operative transport model, condensed phase, crystal growth, gas phase solubility, hydrogen chloride, nonstationary chemical vapor transport experiment, tellurium(IV) chloride, transport agent
 Abstract: Abstract By means of chemical vapor transport reactions (CVT) a variety of solid‐state compounds can be prepared, mostly as impurity free single crystals. Representatives are well‐established for elements, intermetallics, halides, oxides, sulphides, selenides, tellurides, pnictides, and so on. The fundamental thermodynamic principles of CVT reactions are discussed for both single equilibrium reactions (Schaefer model) and more complex reaction mechanisms using the term “gas phase solubility.” Different working techniques for realization of vapor transport experiments are described in detail: application of suitable ampoule materials, furnace assembly, handling of different transport agents, calculation of vapor pressure, experimental procedure. The characteristic vapor transport behavior is described for selected representatives of above‐mentioned classes of solids. Accordingly, some information is given concerning the choice of appropriate transport agent, the evaluation of transport direction, and the viable transport conditions. The simplified deduction or estimation of transport conditions for new compounds of related chemical composition or similar chemical behavior is discussed for the different substance classes. At least, complex thermodynamic modeling of CVT reactions applying the CalPhaD method using freeware is introduced.

Details

show
hide
Language(s): eng - English
 Dates: 2017-06-012017-06-01
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1002/9783527691036.hsscvol2020
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Handbook of Solid State Chemistry
Source Genre: Book
 Creator(s):
Dronskowski, Richard, Editor
Affiliations:
-
Publ. Info: Weinheim : Wiley-VCH
Pages: XXIV, 616 Volume / Issue: 2 Sequence Number: - Start / End Page: 351 - 374 Identifier: ISBN: 978-3-527-69103-6