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  Chemical Bonding in Solids

Miller, G. J., Zhang, Y., & Wagner, F. R. (2017). Chemical Bonding in Solids. In R. Dronskowski (Ed.), Handbook of Solid State Chemistry (pp. 405-489). Weinheim: Wiley-VCH. doi:10.1002/9783527691036.hsscvol5013.

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 Creators:
Miller, Gordon J.1, Author
Zhang, Yuemei1, Author
Wagner, Frank R.2, Author              
Affiliations:
1External Organizations, ou_persistent22              
2Frank Wagner, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863409              

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Free keywords: hydride anions, hydrogen chemistry, metal hydrides, metallic hydrides, oxide structures, oxyhydrides, saline hydrides, solid state chemistry, ternary ionic hydrides, thermodynamic stability
 Abstract: Abstract This chapter discusses the various classes of hydride compounds, with a special focus on saline and metallic hydrides as well as oxyhydrides. It includes the following topics: thermodynamic stability, crystal chemistry, synthesis, and physical properties. The chapter also highlights recent progress in understanding hydride ion mobility in alkaline earth hydrides. It further deals with hydride compounds and in particular those containing alkali, alkaline earth, and transition and rare earth metals. The saline hydrides, that is, AH and AeH2 (with A=Li, Na, K, Rb, and Cs; Ae=Mg, Ca, Sr, and Ba) are proper ionic materials, in which hydrogen is present as hydride anions, H−. Saline hydrides show many similarities with their halide analogues, especially concerning crystal and electronic structures and, perhaps to a lesser extent, physical attributes such as brittleness, hardness, and optical properties.

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Language(s): eng - English
 Dates: 2017-06-012017-06-01
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1002/9783527691036.hsscvol5013
 Degree: -

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Title: Handbook of Solid State Chemistry
Source Genre: Book
 Creator(s):
Dronskowski, Richard, Editor
Affiliations:
-
Publ. Info: Weinheim : Wiley-VCH
Pages: XXIV, 726 Volume / Issue: 5 Sequence Number: - Start / End Page: 405 - 489 Identifier: ISBN: 978-3-527-69103-6