Time-resolved inner-shell photoelectron spectroscopy: From a bound molecule to 
an isolated atom.

Brasse, F.; Goldsztejn, G.; Amini, K.; Boll, R.; Bari, S.; Bomme, C.; Brouard, M.; Burt, M.; de Miranda, B. C.; Düsterer, S.; Erk, B.; Geleoc, M.; Geneaux, R.; Gentleman, A. S.; Guillemin, R.; Ismail, I.; Johnsson, P.; Journel, L.; Kierspel, T.; Kockert, H.; Küpper, J.; Lablanquie, P.; Lahl, J.; Lee, J. W. L.; Mackenzie, S. R.; Maclot, S.; Manschwetus, B.; Mereshchenko, A. S.; Mullins, T.; Olshin, P. K.; Palaudoux, J.; Patchkovskii, S.; Penent, F.; Piancastelli, M. N.; Rompotis, D.; Ruchon, T.; Rudenko, A.; Savelyev, E.; Schirmel, N.; Techert, S.; Travnikova, O.; Trippel, S.; Underwood, J. G.; Vallance, C.; Wiese, J.; Simon, M.; Holland, D. M. P.; Marchenko, T.; Rouzee, A.; Rolles, D.

doi:10.1103/PhysRevA.97.043429

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Time-resolved inner-shell photoelectron spectroscopy: From a bound molecule to an isolated atom.

Brasse, F., Goldsztejn, G., Amini, K., Boll, R., Bari, S., Bomme, C., et al. (2018). Time-resolved inner-shell photoelectron spectroscopy: From a bound molecule to an isolated atom. Physical Review A, 97(4): 043429. doi:10.1103/PhysRevA.97.043429.

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Brasse, F., Author
Goldsztejn, G., Author
Amini, K., Author
Boll, R., Author
Bari, S., Author
Bomme, C., Author
Brouard, M., Author
Burt, M., Author
de Miranda, B. C., Author
Düsterer, S., Author
Erk, B., Author
Geleoc, M., Author
Geneaux, R., Author
Gentleman, A. S., Author
Guillemin, R., Author
Ismail, I., Author
Johnsson, P., Author
Journel, L., Author
Kierspel, T., Author
Kockert, H., Author
Küpper, J., AuthorLablanquie, P., AuthorLahl, J., AuthorLee, J. W. L., AuthorMackenzie, S. R., AuthorMaclot, S., AuthorManschwetus, B., AuthorMereshchenko, A. S., AuthorMullins, T., AuthorOlshin, P. K., AuthorPalaudoux, J., AuthorPatchkovskii, S., AuthorPenent, F., AuthorPiancastelli, M. N., AuthorRompotis, D., AuthorRuchon, T., AuthorRudenko, A., AuthorSavelyev, E., AuthorSchirmel, N., AuthorTechert, S.¹, Author Travnikova, O., AuthorTrippel, S., AuthorUnderwood, J. G., AuthorVallance, C., AuthorWiese, J., AuthorSimon, M., AuthorHolland, D. M. P., AuthorMarchenko, T., AuthorRouzee, A., AuthorRolles, D., Author more..

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1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society, ou_578564

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Abstract: Due to its element and site specificity, inner-shell photoelectron spectroscopy is a widely used technique to probe the chemical structure of matter. Here, we show that time-resolved inner-shell photoelectron spectroscopy can be employed to observe ultrafast chemical reactions and the electronic response to the nuclear motion with high sensitivity. The ultraviolet dissociation of iodomethane (CH3I) is investigated by ionization above the iodine 4d edge, using time-resolved inner-shell photoelectron and photoion spectroscopy. The dynamics observed in the photoelectron spectra appear earlier and are faster than those seen in the iodine fragments. The experimental results are interpreted using crystal-field and spin-orbit configuration interaction calculations, and demonstrate that time-resolved inner-shell photoelectron spectroscopy is a powerful tool to directly track ultrafast structural and electronic transformations in gas-phase molecules.

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Language(s): eng - English

Dates: Published Online: 2018-04-27Date issued: 2018-04

Publication Status: Issued

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Rev. Type: Peer

Identifiers: DOI: 10.1103/PhysRevA.97.043429

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Title: Physical Review A

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Pages: 10 Volume / Issue: 97 (4) Sequence Number: 043429 Start / End Page: - Identifier: -