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Schlagwörter:
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Zusammenfassung:
Using a dynamical version of the Poisson-Boltzmann equation, dynamics of counterion condensation is studied. For a single charged plate in the presence of counterions, it is shown that the approach to equilibrium is diffusive. In the nonequilibrium case of a moving charged plate, a dynamical counterion condensation transition occurs at a critical velocity. The complex dynamic behavior of the counterion cloud is shown to lead to a novel nonlinear force-velocity relation, and an anomalous electrophoresis for the moving charged plate.
