C–H carbonylation: In situ acyl triflates ace it

Lee, Yong Ho; Morandi, Bill

doi:10.1038/nchem.2934

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C–H carbonylation: In situ acyl triflates ace it

Lee, Y. H., & Morandi, B. (2018). C–H carbonylation: In situ acyl triflates ace it. Nature Chemistry, 10(2), 116-117. doi:10.1038/nchem.2934.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0001-6C1F-5 Version Permalink: https://hdl.handle.net/21.11116/0000-0001-6C20-2

Genre: Journal Article

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Creators:
Lee, Yong Ho¹, Author
Morandi, Bill¹, Author

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1Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040309

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Free keywords: Homogeneous catalysis; Synthetic chemistry methodology

Abstract: A simple palladium catalyst has mediated the facile formation of aroyl triflates — an extremely reactive class of electrophiles. These intermediates, generated in situ, enable the Friedel–Crafts acylation of traditionally unreactive arenes, addressing a significant gap in C–H carbonylation methodology.

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Language(s): eng - English

Dates: Published Online: 2018-01-23Date issued: 2018-02-01

Publication Status: Issued

Pages: 2

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Rev. Type: Peer

Identifiers: DOI: 10.1038/nchem.2934

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Title: Nature Chemistry

Abbreviation : Nat. Chem.

Source Genre: Journal

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Publ. Info: London, UK : Nature Publishing Group

Pages: - Volume / Issue: 10 (2) Sequence Number: - Start / End Page: 116 - 117 Identifier: ISSN: 1755-4330
CoNE: https://pure.mpg.de/cone/journals/resource/1755-4330