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  Isodesmic Reactions in Catalysis – Only the Beginning?

Bhawal, B. N., & Morandi, B. (2018). Isodesmic Reactions in Catalysis – Only the Beginning? Israel Journal of Chemistry, 58(1-2), 94-103. doi:10.1002/ijch.201700116.

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Genre: Journal Article

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 Creators:
Bhawal, Benjamin N.1, Author              
Morandi, Bill1, Author              
Affiliations:
1Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040309              

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Free keywords: isodesmic; metathesis; shuttle; catalysis; reversible
 Abstract: In this perspective article, we discuss catalytic isodesmic reactions, a group of chemical reactions that proceed through the redistribution of chemical bonds – i. e. all bonds present in the starting materials are reformed in the products. These reactions are usually reversible and provide a complementary approach to the kinetically controlled strategies traditionally employed in chemical synthesis. To emphasize the power of these reactions across the molecular sciences, we present selected applications of these reactions in organic synthesis, chemical biology, biomass valorization, waste treatment, and materials science. We finally speculate that the development of novel catalytic isodesmic reactions beyond the “classics” (alkene/alkyne metathesis and transfer hydrogenation) holds great promise to solve crucial challenges in synthetic chemistry in the years to come.

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Language(s): eng - English
 Dates: 2017-10-022017-11-172018-02-01
 Publication Status: Published online
 Pages: 10
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/ijch.201700116
 Degree: -

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Title: Israel Journal of Chemistry
  Other : Isr. J. Chem.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: 58 (1-2) Sequence Number: - Start / End Page: 94 - 103 Identifier: ISSN: 0021-2148
CoNE: https://pure.mpg.de/cone/journals/resource/954925408770