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  Near edge x-ray-absorption fine-structure determination of alkyl-chain orientation: Breakdown of the ‘‘building-block’’ scheme

Hähner, G., Kinzler, M., Wöll, C., Grunze, M., Scheller, M., & Cederbaum, L. (1991). Near edge x-ray-absorption fine-structure determination of alkyl-chain orientation: Breakdown of the ‘‘building-block’’ scheme. Physical Review Letters, 67(7), 851-854. doi:10.1103/PhysRevLett.67.851.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0001-9621-0 Version Permalink: https://hdl.handle.net/21.11116/0000-0001-9622-F
Genre: Journal Article
Alternative Title : NEXAFS-determination of alkyl-chain orientation: Breakdown of the 'Building Block' scheme

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PhysRevLett_67_1991_851.pdf (Any fulltext), 203KB
 
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https://journals.aps.org/prl/pdf/10.1103/PhysRevLett.67.851 (Any fulltext)
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Hähner, G., Author
Kinzler, M., Author
Wöll, Ch., Author
Grunze, M.1, Author           
Scheller, M., Author
Cederbaum, L.S., Author
Affiliations:
1Cellular Biophysics, Max Planck Institute for Medical Research, Max Planck Society, ou_2364731              

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 Abstract: The orientation of hydrocarbon chains deposited on surfaces has been studied by near edge x-ray-absorption fine structure (NEXAFS). The so-called ‘‘building-block’’ scheme, which is generally used to predict angular dependences of NEXAFS resonances, is found to be inadequate for C-C σ* resonances in larger molecules, in contrast to previous work [D. A. Outka, J. Stöhr, J. P. Rabe, J. D. Swalen, and H. H. Rotermund, Phys. Rev. Lett. 59, 1321 (1987)]. Using the results of ab initio electronic structure calculations consistent results for several systems containing long hydrocarbon chains could be obtained.

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 Dates: 1991-04-191991-08-12
 Publication Status: Issued
 Pages: 4
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 Rev. Type: Peer
 Identifiers: DOI: 10.1103/PhysRevLett.67.851
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Title: Physical Review Letters
  Abbreviation : Phys. Rev. Lett.
Source Genre: Journal
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Publ. Info: Woodbury, N.Y. : American Physical Society
Pages: - Volume / Issue: 67 (7) Sequence Number: - Start / End Page: 851 - 854 Identifier: ISSN: 0031-9007
CoNE: https://pure.mpg.de/cone/journals/resource/954925433406_1